Material Safety Data Sheet: Sulphamidic Acid

Identification

Product Name: Sulphamidic Acid
Chemical Name: Sulfamic Acid
Synonyms: Amidosulfonic Acid, Aminosulfonic Acid, Sulfamidic Acid, Amidosulphuric Acid
Molecular Formula: H3NSO3
Molecular Weight: 97.09 g/mol
Recommended Uses: Cleaning agent, descaling agent, manufacturing dyes, pH control, herbicides, paper pulp and chlorine stabilization
Manufacturer Information: Information typically supplied by the chemical provider: name, address, emergency contact phone number, and website

Hazard Identification

GHS Classification: Acute toxicity (oral, dermal), Skin irritation, Eye irritation, Specific target organ toxicity-single exposure
Signal Word: Danger
Hazard Statements: Harmful if swallowed, Causes severe skin burns and eye damage, May cause respiratory irritation
Pictograms: Corrosive, exclamation mark
Precautionary Statements: Avoid breathing dust or fumes, Wear protective gloves, eye protection, and face protection, Wash hands thoroughly after handling, Do not eat, drink, or smoke when working with this product, In case of inadequate ventilation, use respiratory protection

Composition / Information on Ingredients

Chemical Name: Sulfamic Acid
CAS Number: 5329-14-6
EC Number: 226-218-8
Concentration: 99-100%
Impurities: Minimal, product generally considered pure; trace impurities dependent on source

First Aid Measures

General Advice: Move exposed individual away from product and contaminated area
Inhalation: Move to fresh air, monitor breathing, administer oxygen if needed, seek medical attention if symptoms persist
Skin Contact: Remove contaminated clothing immediately, rinse affected area with plenty of water for at least 15 minutes, seek medical advice for irritation or burns
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if possible, continue rinsing, seek prompt medical care
Ingestion: Rinse mouth; do not induce vomiting; call poison center or physician right away; never give anything by mouth to an unconscious person

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, foam, dry chemical, carbon dioxide
Unsuitable Extinguishing Media: Strong water jet may spread material
Fire Hazards: Not flammable but thermal decomposition at elevated temperature releases toxic and corrosive fumes — mainly sulfur oxides, nitrogen oxides, possibly ammonia
Special Protective Equipment: Firefighters wear self-contained breathing apparatus and full protective gear, avoid breathing combustion products
Precautions for Firefighters: Use water spray to keep surrounding containers cool, dike runoff water for proper disposal

Accidental Release Measures

Personal Precautions: Wear chemical-resistant gloves, protective eyewear, suitable respiratory protection, avoid creating dust
Environmental Precautions: Prevent product from entering drains or natural waterways, contain spill
Methods for Cleanup: Scoop up spilled material with non-sparking tools, place in a suitable container for disposal, ventilate the area, wash residues away with copious water, avoid raising dust, dispose of waste following local regulations

Handling and Storage

Handling: Use only in well-ventilated areas, minimize dust generation and accumulation, avoid inhalation, ingestion, or skin/eye contact, keep container tightly closed when not in use
Storage Conditions: Store in cool, dry, well-ventilated location away from incompatible substances—bases, oxidants, nitrates, hypochlorites, moisture
Packaging Materials: Store in containers made from compatible corrosion-resistant material, label all vessels clearly
Stock Management: Check inventory regularly for leaks, damaged containers, or unmarked product

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established permissible exposure limit (PEL) or threshold limit value (TLV) by OSHA or ACGIH; dust should not be inhaled
Engineering Controls: Local mechanical exhaust ventilation, process enclosure or other engineering controls to keep exposure levels below recommended limits
Personal Protective Equipment: Chemical splash goggles, face shields, chemical-resistant gloves (nitrile, neoprene, or rubber), long-sleeved protective clothing, dust mask or approved respirator if dust levels exceed recommendations
Hygiene Practices: Remove contaminated clothing before entering eating or break areas, wash thoroughly after handling, do not eat, drink, or smoke in use areas

Physical and Chemical Properties

Appearance: White, odorless crystalline solid
Odor: Odorless
pH (1% solution): 1.18 at 25°C
Melting Point/Range: 205°C (decomposes)
Boiling Point: Decomposes before boiling
Solubility (Water): 213 g/L at 20°C
Vapor Pressure: Negligible
Density: 2.126 g/cm³ at 20°C
Relative Vapor Density: Not applicable
Flash Point: Not applicable
Evaporation Rate: Not applicable
Partition Coefficient (n-octanol/water): Not determined

Stability and Reactivity

Chemical Stability: Stable under recommended handling and storage conditions
Hazardous Reactions: Reacts with strong bases, strong oxidizers, water (under certain conditions)
Conditions to Avoid: Exposure to moisture, high temperature, incompatible materials
Incompatible Materials: Strong bases, oxidizing agents, nitric acid, hypochlorites, moisture
Hazardous Decomposition Products: Decomposition generates sulfur oxides, nitrogen oxides, and possibly ammonia

Toxicological Information

Acute Toxicity: LD50 (oral, rat) 3160 mg/kg
Skin Corrosion/Irritation: Causes burns or severe irritation
Eye Damage/Irritation: Causes serious eye damage
Respiratory Sensitization: May irritate respiratory tract; pre-existing lung conditions may worsen
Carcinogenicity: Not classified as a human carcinogen by IARC, OSHA, or NTP
Mutagenicity: No evidence from animal studies
Symptoms of Exposure: Coughing, shortness of breath, sore throat, eye watering, burns, blistering, stomach pain if ingested

Ecological Information

Ecotoxicity: Harmful to aquatic life in concentrated form; LC50 (fish, 96hr) = 70.3 mg/L (Lepomis macrochirus)
Degradability: Product does not persist in the environment, breaks down rapidly in water
Bioaccumulation Potential: No expected bioaccumulation
Mobility in Soil: Highly water-soluble; likely to move into waterways
Other Adverse Effects: Acidification of water bodies possible in large releases

Disposal Considerations

Waste Disposal Methods: As hazardous waste according to local, regional, and national regulations, neutralize carefully before disposal if permitted
Contaminated Packaging: Triple rinse containers, puncture or crush, dispose of appropriately, do not reuse for other chemicals
Sewage Disposal: Do not discharge into wastewater, natural water, or soil without adequate treatment

Transport Information

UN Number: UN2967
Proper Shipping Name: Sulfamic Acid
Transport Hazard Class: 8 (Corrosive Substance)
Packing Group: III
Label Required: Corrosive
Marine Pollutant: No
Special Transport Precautions: Protect containers from physical damage, moisture, and temperature extremes during transit

Regulatory Information

TSCA (US): Listed on the Toxic Substances Control Act inventory
EINECS (EU): 226-218-8, complies with REACH
Canadian DSL/NDSL: Listed
Hazard Symbol: Corrosive C
Risk Phrases: R22: Harmful if swallowed; R35: Causes severe burns
Safety Phrases: S1/2: Keep locked up and out of reach of children, S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice, S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
Other Regulations: Comply with all applicable governmental regulations in use, handling, transport, labeling, and disposal