Material Safety Data Sheet: Sodium Sulfamate

Identification

Product Name: Sodium Sulfamate
Synonyms: Sodium amidosulfonate, Sodium amidosulfamate
Chemical Formula: NH2SO3Na
CAS Number: 13845-18-6
Recommended Use: Descaling agent, laboratory reagent, industrial cleaning
Manufacturer: Refer to supplier label or purchasing documentation for current producer
Contact Information: Local distributor or supplier contact info highlighted on the package

Hazard Identification

GHS Classification: Eye irritation (Category 2A), Skin irritation (Category 2)
Signal Word: Warning
Hazard Statements: Causes serious eye irritation, causes skin irritation
Pictograms: Exclamation mark (for skin/eye irritant)
Precautionary Statements: Wear eye protection, use gloves, avoid breathing dust, wash hands thoroughly after handling, do not eat/drink while using
Potential Health Effects: Irritates skin and eyes, respiratory tract irritation through inhalation, ingestion may result in stomach upset

Composition / Information on Ingredients

Chemical: Sodium Sulfamate
Concentration: More than 98% purity in most commercial products
Impurities: May contain trace sulfate, ammonia, or water depending on grade
Other Components: No additional ingredients intentionally added

First Aid Measures

Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if possible, seek medical advice if irritation persists
Skin Contact: Remove contaminated clothing, rinse skin with plenty of water, wash with soap if available
Inhalation: Move affected person to fresh air, monitor for difficulty breathing, obtain medical attention if symptoms develop
Ingestion: Rinse mouth with water, avoid inducing vomiting, seek medical help if unwell
Advice for Medical Personnel: Treat symptomatically, monitor for signs of irritation, provide supportive care as needed

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam, carbon dioxide
Unsuitable Extinguishing Media: None known for this material
Specific Hazards: May release toxic fumes including nitrogen oxides, sulfur oxides under fire conditions
Firefighting Instructions: Wear self-contained breathing apparatus, full protective gear, avoid inhaling dust or fumes
Special Protective Equipment: Positive pressure breathing apparatus, chemical-resistant gloves and suit if exposed

Accidental Release Measures

Personal Precautions: Use personal protective equipment, avoid generating dust, ventilate area, avoid eye or skin contact
Environmental Precautions: Prevent large amounts from entering drains, ditches, or waterways, notify authorities if release poses environmental risk
Containment Methods: Sweep up spills without raising dust, transfer to labeled containers for proper disposal
Clean-Up Methods: Wash spill area with water after removing bulk material, dispose rinse water in accordance with regulations

Handling and Storage

Handling: Handle with care to avoid release of dust, keep containers tightly closed, good industrial hygiene is important
Storage: Store in cool, dry, well-ventilated area, keep away from incompatible materials such as strong acids and strong oxidizers, avoid moisture
Specific Uses: Only use for designated industrial or laboratory applications, do not mix with acids unless instructed by process requirements
Incompatible Materials: Acids, strong oxidizing agents, reducing agents
Safe Packaging: Use containers resistant to corrosion, clearly labeled, tightly sealed

Exposure Controls and Personal Protection

Exposure Limits: No occupational exposure limits established, use time-weighted average standards for nuisance dust where available
Engineering Controls: Use local exhaust ventilation, maintain good general ventilation
Personal Protective Equipment: Safety goggles, chemical-resistant gloves (nitrile or neoprene), lab coat or apron, dust mask or respirator in dusty conditions
Hygiene Measures: Wash hands before eating or drinking, remove contaminated clothing, avoid touching face during use
Monitoring: Regularly check workplaces for airborne dust and surface residue, ensure PPE is in good condition

Physical and Chemical Properties

Appearance: White crystalline powder
Odor: Odorless
pH: 5.5–7.5 (solution in water)
Melting Point: Decomposes above 205°C
Boiling Point: Not applicable (decomposes before boiling)
Solubility: Readily soluble in water
Vapor Pressure: Not volatile
Density: Approximately 1.77 g/cm3 at 20°C
Flash Point: Non-flammable solid
Auto-ignition Temperature: Not determined
Other Properties: Stable under normal conditions, produces corrosive vapors on decomposition

Stability and Reactivity

Reactivity: Stable for storage and use under recommended conditions
Chemical Stability: Shows little change when kept dry and away from incompatible substances
Hazardous Reactions: Reacts with acids to release toxic sulfur dioxide or similar gases
Incompatible Materials: Strong acids, oxidizing agents
Decomposition Products: Nitrogen oxides, sulfur oxides, ammonia, sodium compounds may form in fire or when mixed with acids
Condition to Avoid: Contact with moisture, excessive heat, open flames, contamination with acids

Toxicological Information

Routes of Exposure: Inhalation, ingestion, skin contact, eye contact
Acute Toxicity: Low oral and dermal toxicity in animal studies
Chronic Toxicity: No evidence of long-term toxicity from repeat exposure at ordinary handling levels
Skin Irritation: Causes mild to moderate irritation, prolonged use with bare skin worsens effects
Eye Irritation: Severe irritation possible on direct contact, may damage mucous membranes
Inhalation Risks: Dust may cause coughing, sore throat, nasal irritation
Ingestion Effects: Nausea, abdominal pain, vomiting if substantial amounts swallowed
Carcinogenicity: Not listed as carcinogenic by IARC, NTP, OSHA
Other Effects: Does not bioaccumulate, not mutagenic in standard tests

Ecological Information

Ecotoxicity: May harm aquatic organisms at high concentrations, generally low toxicity due to rapid dilution
Persistence and Degradability: Readily dissociates in water, undergoes slow hydrolysis
Bioaccumulative Potential: Does not bioaccumulate in food chains
Mobility in Soil: High mobility in waterlogged soil due to solubility
Other Environmental Hazards: Massive release could alter local water chemistry, leading to temporary impacts on invertebrates and algae

Disposal Considerations

Disposal Methods: Dispose as non-hazardous chemical waste in accordance with local regulations, chemical incineration or landfill accepted in many regions
Packaging Disposal: Rinse and recycle or dispose of containers as chemical waste
Do Not: Flush large amounts to drains or sewers
Additional Advice: Small residues can go to wastewater with plenty of dilution if allowed by authorities, document disposal for compliance

Transport Information

UN Number: Not regulated for most modes of transport
ADR/RID (Road/Rail): Not classified as a dangerous good
IMDG (Marine): Not classed as hazardous for transport
ICAO/IATA (Air): Not classified as hazardous
Packing Group: None assigned
Special Precautions: Transport in sealed containers, prevent moisture exposure in transit, stow away from incompatible substances

Regulatory Information

TSCA Status: Listed in the Toxic Substances Control Act inventory (USA)
EU Regulations: Listed under REACH, not classified as a substance of very high concern
WHMIS Classification: Not controlled in Canada
California Proposition 65: Not listed as a California Proposition 65 chemical
Other National Inventory Listings: Included in Australian, Chinese, Japanese, Korean, and other major inventories
Labeling Required: Irritant symbol, hazard and precautionary statements per GHS globally