MSDS for Sodium 3-(P-Anilinophenylazo)Benzenesulphonate

Identification

Product Name: Sodium 3-(p-Anilinophenylazo)benzenesulphonate
Chemical Formula: C18H14N3NaO3S
CAS Number: 587-98-4
Synonyms: Sodium 4-(4-anilinophenylazo)benzenesulfonate
Recommended Use: Analytical reagent, dye intermediate
Manufacturer: Refer to supplier or distributor label
Contact Information: Manufacturer's phone, emergency contact, and address follow on shipment documentation for safety compliance

Hazard Identification

Hazard Classification: Harmful if swallowed, suspected carcinogen category 2, irritant to skin and eyes
Label Elements: Skull and crossbones symbol, exclamation mark, hazard statements for acute toxicity and irritation
Signal Word: Warning
Hazard Statements: May cause respiratory and skin irritation, ingestion can harm internal organs, potential for allergic skin reaction
Precautionary Statements: Wear protective gloves, do not inhale dust, wash skin after handling, keep container tightly closed, dispose of contents and container for chemical waste
Other Hazards: May stain skin and clothing, dust can irritate mucous membranes and cause coughing

Composition / Information on Ingredients

Chemical Identity: Sodium 3-(p-anilinophenylazo)benzenesulphonate
Common Name: Azo dye intermediate
Concentration: Above 95% in pure technical grade
Impurities: Not typically present in significant quantities; may include sodium chloride and small traces of other sulphonated aromatic compounds if synthesized in non-optimized conditions

First Aid Measures

Inhalation: Move person outside to fresh air, monitor breathing, seek medical attention for persistent cough or breathing issues
Eye Contact: Rinse eyes thoroughly with water at least 15 minutes, open eyelids fully, remove contact lenses after a minute, get medical attention if irritation continues
Skin Contact: Wash exposed area with soap and plenty of water, remove contaminated clothing, dispose of used water properly, seek help for continued irritation or rash
Ingestion: Rinse mouth with clean water, avoid inducing vomiting, get medical help immediately, prepare information on product used and amount swallowed

Fire-Fighting Measures

Suitable Extinguishing Media: Use dry chemical, CO2, foam, or water spray; do not use high-pressure water jet
Specific Hazards: Combustion creates toxic fumes including nitrogen oxides, sulfur oxides, and sodium compounds
Protective Equipment for Firefighters: Wear full protective gear and self-contained breathing apparatus, keep upwind of fire source, avoid breathing smoke
Special Procedures: Cool nearby containers with water spray, prevent runoff from reaching water sources, remove unaffected material if safe

Accidental Release Measures

Personal Precautions: Wear appropriate gloves, chemically resistant boots, and safety goggles, avoid contact with skin and eyes, do not create dust
Environmental Precautions: Recover product quickly, block off drains and waterways, avoid release to environment as chemical can harm aquatic life
Methods for Clean-up: Scoop up spilled material using non-sparking tools, avoid generating dust, place in sealed container, wash residue with sodium carbonate solution then rinse thoroughly, ventilate area

Handling and Storage

Safe Handling: Avoid inhaling dust or ingesting, handle inside chemical fume hood or with local exhaust ventilation, wash hands after work, keep food and drink away from workspace
Storage Conditions: Keep container in cool, dry, well-ventilated space, protect from light and moisture, store apart from oxidizers and acids
Specific Design Considerations: Use clearly labeled containers, maintain good housekeeping, store at ambient temperature, secure away from unauthorized personnel, regular inspection for container integrity encouraged

Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits for this compound
Engineering Controls: Use enclosure solutions like glove box or chemical fume hood, ensure good ventilation, consider HEPA filtration for airborne particulates
Personal Protective Equipment: Nitrile or neoprene gloves, lab coat, safety glasses with side shields, dust-resistant respirator if airborne particles, avoid skin exposure
Hygiene Measures: Remove contaminated clothing before leaving work area, dispose of personal protective equipment based on contamination, do not eat, drink, or smoke in storage or handling areas

Physical and Chemical Properties

Appearance: Orange to reddish-brown powder or crystals
Odor: Slight aromatic odor
pH: Typically between 7-8 in 1% aqueous solution
Melting Point: Decomposes above 200°C
Solubility: Freely soluble in water, slightly soluble in alcohol, insoluble in most organic solvents
Boiling Point: Not applicable due to decomposition
Vapor Pressure: Negligible at room temperature
Relative Density: Approximately 1.34 g/cm³
Partition Coefficient: Data unavailable; likely low due to ionic character
Flammability: Non-flammable but may combust if exposed to strong ignition source
Other Properties: Stable color in solution at neutral pH, sensitive to strong acids and oxidizers

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions, breaks down if exposed to strong light or acids
Hazardous Reactions: Reacts with strong oxidizing agents with possible risk of fire
Conditions to Avoid: Extreme temperatures, acids, light, moisture
Incompatible Materials: Strong oxidizers (sodium hypochlorite, peroxides), strong acids (sulfuric or hydrochloric acids)
Decomposition Products: Produces nitrogen oxides, sodium compounds, and sulfur oxides on combustion
Polymerization Risk: No hazardous polymerization expected

Toxicological Information

Acute Toxicity: Harmful by oral route, lack of significant inhalation toxicity but can irritate respiratory system
Skin Corrosion/Irritation: Can cause irritation, prolonged contact raises risk of allergic reaction
Eye Damage/Irritation: Causes moderate to severe irritation
Respiratory Sensitization: Dust may irritate nose, throat, and lungs
Carcinogenicity: Azo compounds linked to carcinogenic risk in some cases, not classified as proven human carcinogen for this compound
Mutagenicity: Limited data, azo compounds may be mutagenic, handle with caution
Other Effects: Prolonged or repeated exposure to skin may cause dermatitis

Ecological Information

Ecotoxicity: Harmful to aquatic life, can persist in water and soil, decomposition can produce toxic byproducts hazardous to plants and fish
Mobility in Soil: Moderately mobile due to water solubility, can leach to groundwater if not properly contained
Persistence and Degradability: Persists under typical environmental conditions, slow breakdown under natural light and biological processes
Bioaccumulative Potential: Low potential due to ionic structure, not expected to accumulate in aquatic organisms
Other Information: Spills should never be flushed to sewer or water systems, local regulations on discharge apply

Disposal Considerations

Waste Disposal Methods: Collect material in dedicated hazardous waste containers, dispose via licensed chemical disposal contractor
Container Disposal: Triple rinse containers before recycling or incineration under hazardous material guidelines
Environmental Precautions: Do not dump into environment, consult local regulations for specific disposal instructions, avoid contamination of water sources
Special Considerations: Keep disposal records as required under local and federal laws, label all waste clearly

Transport Information

UN Number: Not assigned for this compound; may ship as non-regulated material unless otherwise required
Proper Shipping Name: Chemical, not otherwise specified (refer to shipping documents for classification)
Transport Hazard Class: Not classified under ADR, IMDG, IATA for transport
Packing Group: Not applicable
Special Precautions: Protect from physical damage and moisture, secure against shifting during transit, emergency information must accompany each shipment, comply with regulations for chemical transport in originating and destination countries

Regulatory Information

Inventory Status: Listed in China IECSC, USA TSCA, EU REACH pre-registration/notification may apply
Hazard Symbols Required: GHS hazard pictograms for acute toxicity and irritant effects
Safety Assessment: Handle as regulated laboratory chemical, workplaces must maintain exposure records and risk assessments as outlined by OSHA, REACH, and national guidelines
Labeling Requirements: Comply with GHS standards, show hazard and precaution statements, retain safety instructions on packaging and safety data documentation
Additional Legal Considerations: Subject to workplace exposure limits if set by regional authority, environmental controls required in some regions, waste disposal tracked by licensed contractors