Material Safety Data Sheet (MSDS) – Salicylsulfonic Acid

Identification

Product Name: Salicylsulfonic Acid
Synonyms: 5-Sulfosalicylic Acid, Salicylsulphonate, 2-Hydroxybenzenesulfonic Acid
CAS Number: 97-05-2
Recommended Use: Laboratory reagent, protein precipitant, diagnostic aid
Manufacturer/Supplier: Chemical supply laboratories, commercial scientific vendors
Contact Phone: Reach emergency services for chemical accidents or exposures

Hazard Identification

Classification: Eye damage/irritation (Category 1), Skin irritation (Category 2), Specific Target Organ Toxicity (Single Exposure, Category 3)
Signal Word: Danger
Hazard Statements: Causes serious eye damage, causes skin irritation, may cause respiratory irritation
Pictograms: Corrosive, Exclamation Mark
Precautionary Statements: Use protective gloves, eye protection, and adequate ventilation; avoid inhaling dust and contacting eyes or skin

Composition / Information on Ingredients

Chemical Name: 5-Sulfosalicylic Acid
Molecular Formula: C7H6O6S
Molecular Weight: 218.19 g/mol
Concentration: Pure substance, 100%
Impurities: Trace moisture or inorganic salts possible in commercial lots

First Aid Measures

Eye Contact: Rinse cautiously with water for several minutes. Remove any contact lenses. Seek medical attention immediately.
Skin Contact: Wash thoroughly with soap and large amounts of water. Remove contaminated clothing. If irritation persists, get medical attention.
Inhalation: Move to fresh air. If breathing difficulties or respiratory symptoms develop, call for prompt medical assistance.
Ingestion: Rinse mouth, do not induce vomiting. Drink water if conscious. Seek medical guidance as soon as possible.
Most Important Symptoms: Severe irritation, burns, redness, respiratory discomfort

Fire-Fighting Measures

Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, water spray, foam
Specific Hazards: May liberate toxic and irritating fumes like sulfur oxides or carbon monoxide during combustion
Firefighting Instructions: Firefighters need self-contained breathing equipment and full protective gear. Approach from upwind
Special Equipment: Self-contained breathing apparatus (SCBA), chemical-resistant suit, gloves, eye protection

Accidental Release Measures

Personal Precautions: Wear chemical resistant gloves, goggles, and appropriate respirator if ventilation is inadequate. Avoid breathing dust.
Environmental Precautions: Do not discharge into drains, surface water, or the environment. Contain spill with inert material such as sand or vermiculite.
Cleanup Methods: Scoop or sweep dry product into suitable container for disposal. Wash spill area with large amounts of water. Ventilate area.
Emergency Procedures: Evacuate unnecessary personnel. Isolate contamination area.

Handling and Storage

Handling: Avoid inhalation, ingestion, or skin/eye contact. Use only in chemically protected, well-ventilated environment. Wash hands thoroughly after handling.
Storage: Keep containers tightly closed in a cool, dry, well-ventilated place, away from incompatible substances such as strong bases or oxidizing agents. Use only clearly labeled, chemically compatible containers. Protect from moisture.

Exposure Controls and Personal Protection

Occupational Exposure Limits: Not established. Follow generic guidelines for laboratory chemicals.
Engineering Controls: Use fume hoods or local exhaust ventilation. Keep eyewash and safety showers accessible.
Personal Protective Equipment: Chemical splash goggles or safety glasses, nitrile or neoprene gloves, lab coat or apron, approved respirator during powder transfers.
General Hygiene: Do not eat, drink, or smoke where the chemical is used or stored. Remove contaminated clothing before leaving handling area.

Physical and Chemical Properties

Appearance: White to off-white crystalline powder or granules
Odor: Odorless
pH: Approximately 1.2 at 10 g/L water solution
Melting Point: 120–125°C
Boiling Point: Not determined (decomposes upon heating)
Solubility: Soluble in water and ethanol
Density: 1.74 g/cm³
Vapor Pressure: Negligible at room temperature
Partition Coefficient: No value available
Flash Point: Not flammable under normal conditions

Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions and normal temperature and pressure
Incompatible Materials: Strong oxidizers, strong bases, alkali metals
Hazardous Reactions: Reacts with bases to form salts, generates sulfur oxides when burned
Decomposition Products: Produces toxic gases including sulfur dioxide and carbon monoxide under extreme heat or fire

Toxicological Information

Routes of Exposure: Eyes, skin, inhalation, ingestion
Acute Effects: Causes serious eye damage, skin irritation, respiratory discomfort, gastrointestinal upset when swallowed
Chronic Effects: Data not fully available, repeated exposure may increase risk of dermatitis or sensitization
Toxicity Data: LD50 (oral, rat): 2760 mg/kg
Irritation Data: Causes severe eye injury in animal studies
Carcinogenicity: Not identified as carcinogen by IARC, NTP, OSHA

Ecological Information

Ecotoxicity: Harmful to aquatic organisms in concentrated solutions, large spills may damage aquatic systems
Mobility: Water soluble, likely to move through soil and water if released
Persistence and Degradability: Not expected to persist; potential for biodegradation in typical conditions
Bioaccumulation: Unlikely based on chemical properties
Other Adverse Effects: Minimize release to natural systems

Disposal Considerations

Waste Disposal Methods: Dispose according to federal, state, and local regulations for hazardous chemical waste. Use permitted waste disposal contractors or chemical incineration.
Contaminated Packaging: Rinse empty containers before recycling or disposal.
Special Precautions: Do not mix with non-compatibles in disposal. Avoid discharge to environment.

Transport Information

UN Number: Not classified as hazardous for transport under current regulations
Transport Hazard Class: Not regulated for land, sea, or air
Packing Group: Not applicable
Special Precautions: Prevent package rupture; keep away from food items

Regulatory Information

US Regulations: Not specifically listed under SARA, CERCLA; subject to general chemical regulations. Not on US EPA TSCA Inventory for widespread industrial use.
EU Regulations: Subject to REACH and other chemical safety directives
Label Requirements: Corrosive pictogram, hazard and precautionary statements in accordance with GHS/CLP
Other Local Regulations: Follow workplace chemical safety laws for states or countries where handled