Material Safety Data Sheet (MSDS): Propanesulfonic Acid

Identification

Product Name: Propanesulfonic Acid
Chemical Identity: C3H8O3S
Synonyms: 1-Propanesulfonic acid, 3-Hydroxypropane-1-sulfonic acid
Recommended Use: Laboratory reagent, chemical synthesis, catalyst
Supplier Details: Manufacturer or distributor contact information and emergency telephone number
CAS Number: 109-55-7
UN Number: 2585
EC Number: 203-682-6

Hazard Identification

Classification: Corrosive to metals, skin corrosion/irritation, serious eye damage/irritation
Signal Word: Danger
Hazard Statements: Causes severe skin burns and eye damage, may cause respiratory irritation, harmful if swallowed
Pictograms: Corrosion, Exclamation mark
Precautionary Statements: Do not breathe dust or mist, wash hands after handling, wear protective gloves, clothing, and eye/face protection, use only with adequate ventilation

Composition / Information on Ingredients

Chemical Name: Propanesulfonic Acid
Concentration: Typically >99% by weight
Impurities: Trace water, low-level organic impurities depending on supplier
CAS Number: 109-55-7
EC Number: 203-682-6
Other Ingredients: No significant non-hazardous components reported

First Aid Measures

Inhalation: Remove person to fresh air, keep comfortable for breathing, seek medical help if symptoms develop
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes, remove contaminated clothing, get medical attention
Eye Contact: Rinse cautiously with water for several minutes, remove contact lenses if present and easy to do, continue rinsing, get immediate medical advice
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical care
Notes for Doctors: Treat symptomatically, monitor for respiratory distress, consider risk of chemical pneumonitis
Important Symptoms: Burns, irritation, pain, redness, possible blindness if eyes exposed

Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide depending on surrounding fire
Unsuitable Media: Do not use direct streams of water on burning liquid
Hazards from Fire: May release toxic fumes such as sulfur oxides; container can rupture under intense heat
Protective Equipment: Firefighters wear full protective clothing and self-contained breathing apparatus
Special Instructions: Move containers away from fire area if safe to do so, cool fire-exposed tanks with water spray

Accidental Release Measures

Personal Precautions: Evacuate unnecessary personnel, ensure sufficient ventilation
Protective Equipment: Wear chemical-resistant gloves, goggles, protective suit
Environmental Precautions: Prevent entry to waterways, sewers, basements or confined areas
Spill Cleanup: Absorb spillage with inert material like dry sand, earth or vermiculite and collect in suitable container for disposal
Decontamination: Rinse spill area with plenty of water following cleanup

Handling and Storage

Safe Handling: Use only in areas with adequate ventilation, avoid breathing vapors and contact with skin, eyes, or clothing, handle with appropriate personal protective equipment
Storage Conditions: Store in tightly closed original container in a cool, dry, well-ventilated, corrosion-resistant area away from incompatible substances such as bases, oxidizers, metals
Incompatibilities: Strong bases, strong oxidizers, alkali metals, reducing agents
Special Considerations: Keep away from sources of ignition, protect from physical damage

Exposure Controls and Personal Protection

Exposure Limits: No established occupational exposure limits for Propanesulfonic Acid (consult local regulations)
Engineering Controls: Use fume hood or local exhaust to maintain airborne levels below relevant exposure guidelines
Personal Protective Equipment: Chemical-resistant gloves, safety goggles, face shield, lab coat or apron
Respiratory Protection: Approved respirator when ventilation is inadequate
Hygiene Measures: Wash hands before breaks and after work, remove contaminated clothing and wash before reuse

Physical and Chemical Properties

Appearance: Colorless to pale yellow liquid or crystalline solid
Odor: Slightly pungent, characteristic
Melting Point: 27–35°C
Boiling Point: Decomposes before boiling
Density: Roughly 1.3 g/cm³ at 20°C
Solubility: Highly soluble in water, soluble in alcohol
pH: Strongly acidic in solution
Vapor Pressure: Data not available
Flash Point: Not determined or not applicable
Viscosity: Data not available
Partition Coefficient: No data available

Stability and Reactivity

Stability: Stable under normal conditions with proper storage, hygroscopic
Reactivity: Reacts exothermically with bases and water, can react with metals to release hydrogen
Conditions to Avoid: Contact with incompatible materials, excessive heat, moisture
Hazardous Decomposition: Sulfur oxides, carbon oxides, hydrogen gas with certain metals
Polymerization: Does not undergo hazardous polymerization

Toxicological Information

Routes of Exposure: Skin and eye contact, inhalation, ingestion
Acute Effects: Corrosive, severe burns to skin and eyes, respiratory tract irritation, gastrointestinal burns if swallowed
Chronic Effects: Prolonged exposure may result in chronic skin or eye irritation
Toxicity Data: LD50 (oral, rat): Not precisely available; estimated to be moderately toxic; serious risk at high exposures
Sensitization: Not known to cause sensitization, but potential based on structure
Carcinogenicity, Mutagenicity, Reproductive Toxicity: No classification due to lack of data

Ecological Information

Aquatic Toxicity: Harmful to aquatic organisms due to acidity, may cause long-term adverse effects
Degradability: Expected to be biodegradable; environmental persistence low with neutralization
Bioaccumulation: Not expected to bioaccumulate
Mobility in Soil: High water solubility suggests high mobility
Other Environmental Effects: Large spills can alter local pH and harm microorganisms, plants, and aquatic life

Disposal Considerations

Waste Handling: Dispose of in accordance with local, regional, and national regulations as hazardous chemical waste
Methods: Neutralize with alkali (such as sodium carbonate) and dilute before disposal, collect in appropriate containers
Contaminated Packaging: Rinse thoroughly with water and dispose of according to regulations
Prevention: Do not discharge into sinks, waterways, or soil; use authorized waste management contractors

Transport Information

UN Number: 2585
Proper Shipping Name: Alkane sulfonic acid, liquid, n.o.s. (Propane sulfonic acid)
Transport Hazard Class: 8 (Corrosive substances)
Packing Group: III
Label: Corrosive
Special Precautions: Keep container tightly sealed, upright, protected from damage and extreme temperatures
Regulatory References: Compliant with ADR/RID, IMDG code, IATA/ICAO

Regulatory Information

Global Inventory: Listed on TSCA, EINECS/ELINCS, DSL/NDSL
International Regulations: Subject to regulation under REACH, OSHA Hazard Communication Standard, WHMIS
Labeling: GHS labeling required, including pictograms and hazard statements
Restrictions: Subject to specific worksite controls under local environmental and occupational safety regulations
Other Policies: Ensure all workplace safety practices meet applicable national and international requirements for corrosive chemicals