Material Safety Data Sheet: Dl-6-Oxobornane-10-Sulphonic Acid

1. Identification

Product Name: Dl-6-Oxobornane-10-Sulphonic Acid
Synonyms: Camphorsulfonic acid
Recommended Use: Chemical reagent in organic synthesis and laboratories
Supplier: Information on manufacturer, address, and emergency phone number to be provided by supplier
CAS Number: 5872-08-2
EC Number: 227-529-3

2. Hazard Identification

Classification: Eye irritation (Category 2), Skin irritation (Category 2)
Signal Word: Warning
Hazard Statements: Causes serious eye irritation; Causes skin irritation
Pictograms: Exclamation mark
Precautionary Statements: Wash skin thoroughly after handling, Wear protective gloves/eye protection/face protection, If in eyes: rinse cautiously with water
Physical Hazards: Not classified as flammable or explosive
Health Hazards: Irritates mucous membranes, may cause respiratory irritation when inhaled
Environmental Hazards: Product is not classified as hazardous to the environment under current regulations

3. Composition / Information on Ingredients

Chemical Name: Dl-6-Oxobornane-10-Sulphonic Acid
Chemical Formula: C10H16O4S
Molecular Weight: 232.30 g/mol
Concentration: >98% (analytical purity)
Impurities: None at levels affecting classification
CAS Number: 5872-08-2

4. First Aid Measures

Inhalation: Move person to fresh air, keep at rest in comfortable position, seek medical attention if symptoms persist
Skin Contact: Remove contaminated clothing, rinse skin with copious amounts of water, seek medical attention if irritation develops
Eye Contact: Rinse cautiously with water for at least 15 minutes, lift eyelids occasionally, remove contact lenses, seek immediate medical advice
Ingestion: Rinse mouth, do not induce vomiting, drink water if conscious, seek prompt medical assistance

5. Fire-Fighting Measures

Suitable Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide
Special Hazards: Combustion may produce toxic fumes including sulfur oxides and carbon oxides
Protective Equipment: Firefighters should wear self-contained breathing apparatus and full protective clothing
Special Information: Prevent runoff from entering drains or watercourses

6. Accidental Release Measures

Personal Precautions: Use personal protective equipment, avoid contact with skin, eyes, and clothing, ensure proper ventilation
Environmental Precautions: Prevent entry to surface water, drains, and groundwater systems
Containment: Collect spillage, sweep up without creating dust, store in suitable closed containers for disposal
Cleaning Up: Wash area with plenty of water after the product is picked up, ventilate space thoroughly

7. Handling and Storage

Handling: Handle in a chemical fume hood, avoid inhalation of dust and contact with skin and eyes, use only with adequate ventilation, do not eat, drink, or smoke while handling
Storage Conditions: Store tightly closed in a cool, dry, well-ventilated area, keep away from incompatible substances such as strong bases and oxidizers
Storage Class: Chemical storage, corrosive solids
Packaging: Use chemically resistant, sealed containers

8. Exposure Controls and Personal Protection

Engineering Controls: Use local exhaust or general room ventilation to reduce dust exposure
Occupational Exposure Limits: Not established for this compound
Personal Protective Equipment: Safety goggles or face shield, acid-resistant gloves, laboratory coat, suitable respirator when airborne dust is present
Hygiene: Wash hands before breaks and after work, remove contaminated clothing and wash before reuse, do not touch face or exposed skin with contaminated gloves or clothes

9. Physical and Chemical Properties

Appearance: White to off-white crystalline solid
Odor: Odorless or slight characteristic odor
Odor Threshold: Not applicable
pH: Acidic in solution (1% solution pH typically around 1-2)
Melting Point/Freezing Point: 196-200°C
Boiling Point: Decomposes before boiling
Flash Point: Not determined
Flammability: Not flammable
Vapor Pressure: Negligible at room temperature
Solubility: Soluble in water, moderately soluble in alcohol
Partition Coefficient: Not determined
Decomposition Temperature: >200°C
Viscosity: Not applicable

10. Stability and Reactivity

Chemical Stability: Stable under recommended storage conditions
Reactivity: May react with strong bases, oxidizing agents, carbonates, and reducing agents
Possibility of Hazardous Reactions: Generates toxic sulfur oxides and carbon oxides under fire conditions or when heated to decomposition
Conditions to Avoid: Excess heat, contact with incompatible materials, exposure to moisture over extended periods
Incompatible Materials: Strong oxidizers, strong bases, reactive metals such as sodium or potassium
Hazardous Decomposition Products: Sulfur oxides, carbon oxides, and other toxic vapors

11. Toxicological Information

Likely Routes of Exposure: Inhalation, ingestion, skin and eye contact
Acute Effects: Irritates eyes, skin, and respiratory system; can cause burning sensations, redness, and pain
Chronic Effects: Prolonged or repeated exposure can cause dermatitis or eye damage
Toxicity Data (Animal Studies): No detailed LD50 values available for this compound, but similar sulfonic acids show low to moderate acute oral toxicity in rats (200-2000 mg/kg)
Carcinogenicity: Not listed by IARC, NTP, or OSHA as carcinogen
Mutagenicity: No data
Sensitization: No evidence of skin sensitization reported

12. Ecological Information

Ecotoxicity: Not classified as environmentally hazardous, but large quantities may alter local pH and adversely affect sewage treatment and aquatic organisms
Persistence and Degradability: Expected to be biodegradable, may persist in soil and water in the absence of microbial activity
Bioaccumulative Potential: Low likelihood of bioaccumulation due to solubility in water
Mobility in Soil: Mobile in water, may migrate in soil, especially in acidic environments
Other Adverse Effects: Avoid large volume discharge to natural water systems

13. Disposal Considerations

Disposal Methods: Dispose of in accordance with local, regional, and national regulations, as hazardous laboratory waste
Contaminated Packaging: Empty containers must be treated as hazardous, rinse thoroughly with water before recycling or disposal
Special Precautions: Chemical waste should not enter drains, sewers, or water bodies; coordinate disposal with licensed chemical waste disposal company

14. Transport Information

UN Number: Not regulated for transport according to most international regulations
Proper Shipping Name: Not classified as a dangerous good by transport agencies
Transport Hazard Class: Not assigned
Packing Group: Not assigned
Environmental Hazards: Not a Marine Pollutant
Special Precautions: Keep container securely closed, prevent spillage, consult transport provider for any additional precautions

15. Regulatory Information

EU Regulations: Not listed under REACH Annex XIV or SVHC, CLP classification applies for irritant hazards
US Regulations: Not listed on TSCA as restricted substance; no CERCLA reportable quantity
Canada: DSL/NDSL listing required by supplier; classified as not hazardous according to WHMIS
Other International Regulations: Consult local chemical safety agencies for applicability, follow country- and region-specific rules concerning chemical handling and labeling
Label Elements: GHS-compliant labeling for irritant effects