Product Name: Calcium Bis(Trifluoromethanesulfonate)
Chemical Formula: Ca(CF3SO3)2
Synonyms: Calcium triflate, Calcium trifluoromethanesulphonate
Recommended Use: Electrolyte in batteries, chemical synthesis, catalyst applications
Manufacturer: [Insert Manufacturer Details]
Emergency Contact: Local Poison Control Center or corresponding safety authority
CAS Number: 42135-25-9
Molecular Weight: 394.22 g/mol
Physical Appearance: White crystalline solid, odorless
Contact Phone Number: [Insert Emergency Number]
Hazard Classification: Not classified as hazardous according to GHS criteria for this material
Signal Word: None
Hazard Statements: May cause mild skin and eye irritation; dust may cause discomfort in respiratory tract
Pictograms: No specific pictograms
Precautionary Statements: Avoid breathing dust, wash thoroughly after handling, use only outdoors or in well-ventilated area
Potential Health Effects: Eye, skin, respiratory tract irritation; ingestion can result in discomfort but no severe toxicity reported in typical use
Chemical Name: Calcium Bis(Trifluoromethanesulfonate)
Concentration: ≥98%
CAS Number: 42135-25-9
Impurities: Typically includes trace residual solvents or moisture
Additives: No other ingredients considered hazardous under OSHA Hazard Communication Standard
Inhalation: Move person to fresh air. Seek medical attention if symptoms persist. Provide oxygen if breathing is difficult.
Skin Contact: Remove contaminated clothing. Wash affected skin thoroughly with soap and water. Contact a physician if irritation develops.
Eye Contact: Rinse eyes cautiously with water for at least 15 minutes, lifting eyelids. Remove contacts if present and easy to do. Medical attention for persistent irritation.
Ingestion: Rinse mouth with water. Do not induce vomiting unless instructed by medical personnel. Drink water to dilute. Medical advice if symptoms develop.
Suitable Extinguishing Media: Use dry chemical, CO2, foam, or water spray. Use what is appropriate for the surrounding fire.
Hazardous Combustion Products: Releases toxic and corrosive vapors including hydrogen fluoride, sulfur oxides, carbon oxides, calcium oxides.
Specific Hazards: Fine powder can form explosive mixtures in air. Material not flammable but thermal decomposition at high temperatures creates toxic gases.
Protective Equipment for Firefighters: Wear full protective gear, including self-contained breathing apparatus.
Personal Precautions: Evacuate unnecessary personnel. Wear suitable protective clothing, gloves, goggles. Avoid dust formation.
Environmental Precautions: Do not allow material to reach drains, surface water, or soil. Prevent further leakage or spillage if safe.
Methods for Cleanup: Sweep up and collect in suitable containers for proper disposal. Ventilate the area. Wash spill area with plenty of water. Dispose in accordance with local, regional, national regulations.
Handling: Minimize dust generation and accumulation. Handle in a controlled, well-ventilated workspace. Avoid inhalation and direct contact with skin and eyes. Use protective equipment as appropriate.
Storage: Store in a cool, dry, well-ventilated place, away from strong oxidizers, acids, and sources of ignition. Keep container tightly closed when not in use. Use containers compatible with strong salts. Avoid exposure to moisture to maintain chemical stability.
Engineering Controls: Local exhaust ventilation recommended to control airborne concentrations. Safety shower and eyewash station in the work area.
Respiratory Protection: Use NIOSH/MSHA-approved respirator where airborne dust exceeds exposure limits. For nuisance levels, a dust mask suffices.
Hand Protection: Impervious gloves preferred (nitrile, PVC).
Eye Protection: Chemical safety goggles required.
Skin Protection: Long-sleeved clothing, lab coat recommended.
Hygiene Measures: Wash hands before breaks, after handling, and at end of work. Remove contaminated clothing and wash before reuse.
Appearance: White, odorless crystalline powder
Odor: None
Melting Point: Above 300°C (decomposes before melting)
Boiling Point: Not available (decomposes)
Flash Point: Not flammable
Vapor Pressure: Not applicable
Solubility: Freely soluble in water, soluble in methanol and other polar solvents
Density: Approx. 2.0 g/cm3 (experimental context may vary)
pH (1% solution): Slightly acidic (typically between 3 and 6)
Decomposition Temperature: Over 300°C
Partition Coefficient: Not determined
Chemical Stability: Stable under normal handling and storage conditions. Moisture can promote slow hydrolysis.
Hazardous Reactions: Contact with strong oxidizers or acids can cause decomposition.
Conditions to Avoid: Excess moisture, high temperatures, open flames, incompatible materials.
Incompatible Materials: Strong acids, strong oxidizers, bases. Water in excess may affect product quality.
Hazardous Decomposition Products: Emits hydrogen fluoride, sulfur oxides, carbon oxides, and calcium oxides on thermal decomposition.
Acute Toxicity: Oral, dermal, and inhalation exposure in animal studies have not resulted in significant adverse effects at levels associated with laboratory and industrial use.
Skin Corrosion/Irritation: Repeated or prolonged contact may cause irritation or redness.
Eye Effects: Dust particles are irritating to eyes and may cause transient redness or discomfort.
Inhalation: May lead to mild respiratory tract discomfort, coughing, or sore throat.
Ingestion: Low toxicity is expected, but larger amounts could upset the gastrointestinal tract.
Chronic Effects: Long-term exposure studies not widely conducted; handle with standard caution for synthetic chemicals.
Carcinogenicity: Not listed as carcinogenic by NTP, IARC, or OSHA.
Mutagenicity: No data indicating mutagenic potential.
Reproductive Effects: No information available.
Eco-toxicity: Not classified as hazardous to aquatic life at common concentrations, but large spills may impact aquatic organisms.
Persistence and Degradability: Inorganic metal salts ultimately persist as ions. Organic moieties slowly degrade.
Bioaccumulation Potential: Limited bioaccumulation expected due to high solubility and ionization in water.
Mobility in Soil: High mobility expected as ions in water-rich environments.
Other Adverse Effects: Improper disposal may increase water salinity and affect sensitive ecosystems, especially in confined or poorly flushed water bodies.
Product Disposal: Dispose of unused material as hazardous waste following federal, state, and local laws. Consult local regulatory authorities for appropriate landfill or incineration options.
Container Disposal: Rinse empty containers thoroughly. Dispose or recycle in accordance with regional requirements.
Environmental Precautions: Do not dispose into drains, surface water, or soil. Prevent further environmental contamination from large quantities.
UN Number: Not regulated for transport under international guidelines.
Proper Shipping Name: Not regulated
Transport Hazard Class: Not regulated (no specific hazard identified under international transport regulations)
Packing Group: Not required
Marine Pollutant: No
Special Precautions: Ensure containers remain closed and protected from moisture during transit; label clearly with chemical identity.
TSCA (Toxic Substances Control Act): Listed in the United States TSCA Inventory
REACH (EU): Compliance required for manufacturers and importers above 1 metric ton per year
OSHA (US): Not classified as hazardous under current criteria
WHMIS (Canada): Not specifically controlled
SARA Title III Sections 302, 311/312, 313: Not listed as a hazardous chemical under these sections
EINECS/ELINCS: Listed under 255-050-5
DSL/NDSL (Canada): Registered
Other Regulations: Review local, regional, and national requirements for storage, handling, and disposal of specialty chemicals. Labels and slip sheets must state the identity and any advised hazards for workplace safety.
