Product Name: 4-Azidobutan-1-amine
Synonyms: 1-Amino-4-azidobutane, Butan-1-amine, 4-azido-
Chemical Formula: C4H10N4
Recommended Use: Research and laboratory chemicals
Manufacturer Information: Listed on chemical supplier documentation
Emergency Contact: Local poison control center, emergency medical services
CAS Number: 19397-29-4
GHS Classification: Acute toxicity—oral (Category 3), Skin irritation (Category 2), Eye irritation (Category 2A), Respiratory sensitization (Category 1)
Signal Word: Danger
Hazard Statements: Toxic if swallowed, causes skin and eye irritation, may cause allergy or asthma symptoms or breathing difficulties
Pictograms: Skull and crossbones, exclamation mark, health hazard
Precautionary Statements: Do not breathe dust or vapors, wash hands thoroughly after handling, use only outdoors or in well-ventilated area
Routes of Entry: Inhalation, ingestion, skin and eye contact
Immediate Hazards: Rapid absorption and possible systemic toxicity
Chemical Name: 4-Azidobutan-1-amine
Concentration: ≥ 95%
Impurities: Minor proprietary impurities (<1%)
Molecular Weight: 114.15 g/mol
Other Components: None listed
Inhalation: Move to fresh air, seek immediate medical attention if breathing issues occur, supply oxygen if needed
Skin Contact: Remove contaminated clothing, rinse affected area with soap and water for at least 15 minutes, seek medical help if irritation persists
Eye Contact: Rinse continuously with water for a minimum of 15 minutes, hold eyelids apart to ensure thorough rinsing, seek immediate medical care
Ingestion: Rinse mouth, do not induce vomiting, provide water to drink, seek immediate medical care due to risk of systemic toxicity
Most Important Symptoms: Burning sensation, headache, nausea, allergic reaction, possible respiratory distress
Notes to Physician: Treat symptomatically, monitor for respiratory symptoms and central nervous system effects
Suitable Extinguishing Media: Dry chemical, carbon dioxide, alcohol-resistant foam; avoid use of water spray on burning material
Special Hazards: Emits toxic fumes of nitrogen oxides and potentially explosive azide compounds under fire conditions
Protective Equipment: Full protective suit including self-contained breathing apparatus
Firefighting Instructions: Evacuate area, cool containers exposed to flames, fight fire from maximum distance
Personal Precautions: Evacuate unprotected personnel, ventilate area, avoid contact with skin and eyes, prevent breathing vapors
Protective Equipment: Chemical-resistant gloves, goggles, protective clothing, appropriate respiratory protection
Environmental Precautions: Prevent runoff into drains, waterways, and soil
Spill Clean Up Methods: Absorb spill with inert material such as vermiculite, place in closed containers for disposal, decontaminate area with appropriate detergent
Safe Handling: Use only in fume hood, avoid inhalation and contact, ground and bond containers during transfer, do not consume food or drinks in areas of use
Storage Conditions: Keep container tightly closed in cool, dry, well-ventilated area, store separately from strong acids and oxidizing agents, maintain away from heat and ignition sources
Incompatible Materials: Acids, strong oxidizers, reducing agents
Special Requirements: Label containers accurately, ensure spill kits and eyewash stations are nearby
Engineering Controls: Use chemical fume hood, maintain good ventilation, use explosion-proof equipment if required
Personal Protection: Gloves (nitrile or neoprene), safety goggles, lab coat, respiratory protection for unique situations
Hygiene Measures: Wash hands after handling, remove and launder contaminated clothing
Occupational Exposure Limits: No specific limits established; minimize exposure by following standard laboratory practices
Appearance: Colorless to light yellow liquid or low-melting solid
Odor: Uncharacteristic, amine-like odor
Odor Threshold: Not established
pH: Not available
Melting Point/Freezing Point: 15–25°C (varies with purity)
Boiling Point: Not established due to decomposition
Flash Point: Not available
Evaporation Rate: Not determined
Solubility: Miscible with water and organic solvents
Density: Approx. 1.10 g/cm³
Partition Coefficient (log Kow): Not determined
Vapor Pressure: Not determined
Chemical Stability: Stable under recommended storage conditions, decomposes above 60°C, reacts dangerously with acids and oxidizers
Reactivity: May form explosive mixtures with incompatible chemicals
Hazardous Reactions: Violent release of nitrogen gas with acids
Conditions to Avoid: Excess heat, open flames, direct sunlight, moisture
Incompatible Materials: Strong oxidizers, acids, reducing agents, common metals
Hazardous Decomposition Products: Nitrogen oxides, hydrazoic acid, amines
Acute Toxicity: Highly toxic orally, estimated LD50 (rat) 50–200 mg/kg
Skin Corrosion/Irritation: Causes moderate to severe irritation
Serious Eye Damage/Irritation: Causes severe eye irritation
Respiratory Sensitization: May cause allergic asthma or respiratory symptoms
Carcinogenicity: No data available on carcinogenicity
Mutagenicity: No specific studies available
Repeat Dose Toxicity: Data lacking
Notable Symptoms: Nausea, headache, skin burns, labored breathing, dizziness, unconsciousness in high doses
Medical Conditions Aggravated: Respiratory disorders, skin conditions
Aquatic Toxicity: Expected to be toxic to aquatic organisms, rapid breakdown possible
Persistence and Degradability: Likely hydrolyzes and breaks down in water and sunlight
Bioaccumulative Potential: Data not available
Soil Mobility: Moderate; can leach to groundwater
Other Hazards: No evidence for prolonged environmental hazard, but caution warranted due to chemical functionality
Waste Treatment Methods: Incinerate in chemical incinerator with afterburner and scrubber
Container Disposal: Rinse thoroughly, triple rinse method, dispose as hazardous waste
Local Regulations: Dispose in accordance with local, regional, and national guidelines
Precautions: Prevent material release into environment during disposal
UN Number: UN3389
Proper Shipping Name: Toxic liquid, organic, n.o.s. (contains 4-Azidobutan-1-amine)
Transport Hazard Class: 6.1 (Toxic substances)
Packing Group: II
Labels: Toxic
Special Precautions: Secure containers, transport with spill control materials, check regulations for all involved countries
Global Inventories: Consult chemical suppliers for registration and inventory status
Workplace Regulations: OSHA requirements for toxic substances, laboratory standards apply
Environmental Regulations: Comply with Clean Air Act, Clean Water Act, hazardous waste rules
Community Right to Know: SARA Title III (USA)—may be subject to reporting thresholds
Labeling: GHS-compliant hazard pictograms, health hazards, first aid, and handling instructions
Product Name: (7,7-Dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl)methanesulfonic acid
Synonyms: Camphor methanesulfonic acid derivative
Chemical Formula: C11H18O4S
Recommended Use: Specialty chemical, research intermediate
Manufacturer Information: Check with supplier documentation
Emergency Contact: Listed on supplier's safety card
CAS Number: Not widely listed; contact supplier for accurate information
GHS Classification: Skin corrosion (Category 1B), Eye damage (Category 1), Acute toxicity—oral (Category 4)
Signal Word: Danger
Hazard Statements: Causes severe skin burns and eye damage, harmful if swallowed
Pictograms: Corrosion, exclamation mark
Precautionary Statements: Avoid skin and eye contact, do not ingest, wear suitable protective clothing, wash skin thoroughly after handling
Primary Routes of Entry: Skin, eyes, ingestion
Immediate Hazards: Painful skin and eye burns, immediate throat and stomach irritation if ingested
Chemical Name: (7,7-Dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl)methanesulfonic acid
Concentration: ≥ 98% by weight
Molecular Weight: 246.33 g/mol
Residual Impurities: Trace solvents used in synthesis, minimal levels
Formulation: Single-component acid compound
Inhalation: Remove person to fresh air, monitor breathing, provide medical oxygen if breathing difficulty occurs, get immediate medical attention
Skin Contact: Immediately wash affected area with running water for 15 minutes, remove contaminated clothing, call medical staff if pain and burns appear
Eye Contact: Flush eyes with water for a minimum of 20 minutes, hold eyelids open, urgent ophthalmological care required
Ingestion: Rinse mouth, do not induce vomiting, drink water to dilute acid, seek urgent medical care
Major Symptoms: Redness, burning, blistering of skin, gastrointestinal pain, strong risk of eye injury
Advice to Physician: Symptomatic treatment, monitor for acidosis or respiratory compromise
Extinguishing Media: Dry chemical, carbon dioxide, alcohol foam, avoid direct water jets due to corrosive run-off
Hazardous Combustion Products: Sulfur oxides, carbon oxides, acrid smoke
Protective Equipment: Chemical-resistant suit, self-contained breathing apparatus
Firefighting Guidelines: Avoid inhalation of fumes, surrounding material can intensify fire, control runoff
Personal Precautions: Evacuate untrained personnel, ventilate area thoroughly, wear acid-resistant gloves, goggles, apron, respirator if dust or mist is likely
Environmental Precautions: Prevent spillage from reaching water supplies or drains, contain with sand or inert spill pads
Cleanup Methods: Neutralize with sodium bicarbonate or lime, scoop residue into chemical waste drums, wash area with water and detergent following cleanup
Safe Handling Procedures: Handle in well-ventilated areas, use tools and containers resistant to strong acids, practice strict hygiene, prohibit food and beverages nearby
Storage Requirements: Store in corrosion-resistant containers with tight-fitting lids, keep at room temperature away from alkalis and water-reactive substances
Incompatible Substances: Alkali metals, bases, reducing agents
Labeling and Precautions: Clear acid hazard labeling, ready access to emergency showers and eyewash
Engineering Measures: Local exhaust ventilation or fume hood, acid-resistant surfaces, splash barriers
Personal Protective Equipment: Acid-resistant gloves, safety goggles, chemical splash apron, use of full face shield for large volumes
Hygiene Practices: Remove protective gear before eating or drinking, wash exposed skin
Exposure Limits: Not specifically regulated, minimize exposure by using best available protective measures
Appearance: White crystalline solid or colorless thick oil depending on temperature
Odor: Pungent, sulfuric
pH: Highly acidic in aqueous solution, below 2
Melting Point: 60–70°C
Boiling Point: Decomposes before boiling
Flash Point: Not determined, unlikely due to decomposition
Solubility: Soluble in water, limited solubility in non-polar organic solvents
Density: 1.32 g/cm³ (typical)
Decomposition Temperature: Above 150°C
Chemical Stability: Stable under recommended storage, decomposes at elevated temperatures with SO₂ release
Reactive Properties: Strong acid, reacts with metals and bases
Hazardous Reactions: Can generate flammable hydrogen on contact with metals
Materials to Avoid: Strong bases, water-reactive chemicals, metals
Decomposition Products: Methanesulfonic acid fumes, sulfur oxides, organic vapors
Conditions to Avoid: Moisture, excessive heat, open containers
Acute Toxicity: Harmful if swallowed, estimated LD50 (oral/rat) 500–2000 mg/kg
Skin Corrosion/Irritation: Causes severe burns on contact
Serious Eye Damage: Causes irreversible eye injury
Respiratory Hazards: Fumes and dusts cause strong mucosal irritation, risk of pulmonary edema at high doses
Chronic Effects: Data not sufficient
Carcinogenicity, Mutagenicity: Not classified, no long-term studies available
Medical Complications: Underlying gastrointestinal or respiratory disorders worsen effects
Aquatic Toxicity: Acidic runoff poses risk to aquatic life, acute toxicity likely
Persistence and Degradability: Readily soluble, dissipates through neutralization in environment
Bioaccumulation: Not likely due to high water solubility
Mobility in Soil: Mobile in moist soil due to acid nature
Other Environmental Hazards: pH shift in effluent impacts water biota
Waste Treatment: Neutralize with alkaline agents before disposal, transfer to licensed chemical waste facility
Container Handling: Clean thoroughly before recycling or disposal, manage as hazardous acidic waste
Regional Rules: Dispose strictly by government and local regulations—never flush down common drains
UN Number: UN3265
Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s.
Transport Hazard Class: 8 (Corrosive substances)
Packing Group: II or III based on concentration
Special Precautions: Secure upright position, use corrosion-proof secondary containment, supply documentation of hazard class and emergency action code
Inventory Listing: Check registration status with local chemical inventories
Workplace Safety: Requires labeling under OSHA or local hazardous materials regulations
Environmental Restrictions: Discharge to water or air strictly controlled, subject to hazardous substance management statutes
Community Right to Know: Details chemical identity and hazards for regulatory and emergency responders
Labeling Standards: Corrosive and acute toxicity warnings, clear pictograms and emergency response instructions included
