Material Safety Data Sheet: 3-Nitro Benzene Sulfonic Acid Sodium Salt

Identification

Product Name: 3-Nitro Benzene Sulfonic Acid Sodium Salt
Other Names: Sodium 3-nitrobenzenesulfonate, meta-Nitrobenzenesulfonic acid sodium salt
CAS Number: 127-68-4
Recommended Use: Dye intermediate, analytical reagent, chemical synthesis
Supplier: Chemical manufacturer or distributor details required for traceability

Hazard Identification

Classification: Eye irritation, skin irritation, respiratory tract irritant
Label Elements: Hazard pictograms for irritant and aquatic hazard, warning symbol
Hazard Statements: Causes skin and eye irritation, may cause respiratory discomfort, harmful to aquatic life
Precautionary Statements: Avoid breathing dust or powder, wear protective gloves, use eye and face protection, wash thoroughly after handling

Composition / Information on Ingredients

Chemical Name: 3-Nitrobenzenesulfonic acid sodium salt
Synonyms: Sodium 3-nitrobenzene sulfonate
Molecular Formula: C6H4NO5SNa
Molecular Weight: 225.15 g/mol
Concentration: 98-100% pure (typical for industrial grade)

First Aid Measures

Eye Contact: Rinse eyes under running water for at least 15 minutes, keep eyelids apart, remove contact lenses, seek medical attention
Skin Contact: Remove contaminated clothing, rinse skin thoroughly with soap and water, seek medical advice if irritation develops
Inhalation: Move to fresh air, keep patient comfortable, seek medical help if breathing difficulty persists
Ingestion: Rinse mouth, do not induce vomiting, seek immediate medical attention if large amounts swallowed or symptoms occur

Fire-Fighting Measures

Suitable Extinguishing Media: Dry chemical, carbon dioxide, water spray, foam
Unsuitable Extinguishing Media: Direct water stream may cause contamination and spread
Special Hazards: May produce toxic fumes under fire, including nitrogen oxides and sulfur oxides
Special Protective Equipment: Firefighters wear self-contained breathing apparatus and chemical protective clothing

Accidental Release Measures

Personal Precautions: Avoid inhalation, contact with skin and eyes, ventilate area
Environmental Precautions: Prevent runoff into sewers or waterways, alert local authorities in case of spillage
Methods for Cleaning Up: Contain spill with inert material like sand, transfer to a suitable closed container, wash area with water avoiding splash

Handling and Storage

Handling: Handle in well-ventilated places, avoid dust generation, do not eat, drink or smoke while using
Storage: Store in tightly sealed container, keep away from incompatible materials such as strong reducing agents or acids, store in cool, dry location out of direct sunlight

Exposure Controls and Personal Protection

Occupational Exposure Limits: No established limits, use best industrial hygiene practices
Engineering Controls: Local exhaust ventilation recommended
Personal Protection: Chemical-resistant gloves, safety goggles or full face shield, protective clothing, use of NIOSH-approved respirator if dust exposure is possible

Physical and Chemical Properties

Appearance: Yellow to orange crystalline powder
Odor: Odorless or very mild aromatic odor
pH: 7-9 (1% solution in water)
Melting Point: Decomposes above 300°C
Boiling Point: Decomposes
Solubility: Soluble in water
Vapor Pressure: Negligible
Density: Approx. 1.7 g/cm³
Flash Point: Not flammable
Stability: Stable under recommended conditions

Stability and Reactivity

Chemical Stability: Stable under normal storage and handling
Conditions to Avoid: Excessive heat, direct sunlight, contact with acids or reducing agents
Incompatible Materials: Strong acids, strong reducers, organic materials
Hazardous Decomposition: Toxic gases including sulfur oxides, nitrogen oxides can form upon decomposition

Toxicological Information

Acute Toxicity: Data limited, expected to have low oral toxicity, may be irritating to digestive tract
Skin Irritation: Causes redness, possible rash upon contact
Eye Irritation: Irritating, may lead to redness, pain, possible swelling
Respiratory Effects: Dust inhalation may cause coughing, throat irritation, difficulty breathing
Chronic Exposure: Long-term exposure can promote dermatitis, possible sensitization not fully studied
Carcinogenicity: Not classified by IARC, NTP, or OSHA

Ecological Information

Aquatic Toxicity: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Persistence and Degradability: Not readily biodegradable, can persist in water/soil
Bioaccumulation: Low potential for bioaccumulation
Mobility in Soil: Expected to have moderate mobility, water solubility allows for movement through soil layers

Disposal Considerations

Waste Disposal Methods: Dispose of in accordance with local, regional, national, and international regulations, incinerate in suitable facility or landfill as allowed
Contaminated Packaging: Rinse containers and offer for recycling or disposal as hazardous waste

Transport Information

UN Number: Not regulated under most international transport codes
Transport Hazard Class: Not classified as hazardous for transport
Packing Group: Not assigned
Environmental Hazards: Not a marine pollutant
Special Precautions: Keep packaging intact, prevent spillage during transport

Regulatory Information

National Regulations: Check local workplace, environmental safety regulations for classification
International Inventories: Listed on chemical inventories including TSCA (USA), EINECS (EU), DSL (Canada), AICS (Australia)
Other Regulatory Status: Not subject to any specific restrictions beyond general chemical safety rules