Material Safety Data Sheet for 2,4-Xylene Sulfonic Acid

Identification

Product Name: 2,4-Xylene Sulfonic Acid
Chemical Formula: C8H10SO3
Synonyms: 2,4-Dimethylbenzene Sulfonic Acid
CAS Number: 15717-53-6
Recommended Use: Intermediate for dyes, surfactants, pharmaceuticals
Manufacturer Information: Supplier details readily available on the packaging or company website, with 24/7 emergency contact phone numbers to reach technical support and leak response teams.

Hazard Identification

Hazard Classification: Corrosive, serious eye damage, skin irritant, harmful if swallowed
Signal Word: Danger
Hazard Statements: Causes severe skin burns, serious eye damage, may cause respiratory irritation or coughing if inhaled
Pictograms: Corrosive, exclamation mark
Precautionary Statements: Avoid all contact with skin, eyes, and clothing. Do not breathe dust or fumes. Wash thoroughly after handling. Wear impervious gloves, goggles, and full protective clothing to reduce risk.

Composition / Information on Ingredients

Chemical Identity: 2,4-Xylene Sulfonic Acid
Purity: ≥ 98%
Impurities: Contains trace amounts of other xylene sulfonic acid isomers, water content below 2%, and negligible heavy metals
Concentration Range: Main component comprises the majority of the mixture by weight; no hazardous impurities above threshold limits

First Aid Measures

Inhalation: Relocate immediately to fresh air, keep airways open, seek prompt medical advice if breathing becomes difficult or person feels weak
Skin Contact: Remove all contaminated clothing, wash skin thoroughly with running water and mild soap for minimum fifteen minutes, do not delay medical evaluation for persistent irritation, blisters or pain
Eye Contact: Rinse eyes carefully using clean, running water for at least twenty minutes, mind the eyelids and eyeballs directly, see eye specialist immediately after first aid
Ingestion: Rinse mouth with water (never give anything, even water, to someone unconscious), do not induce vomit, seek immediate attention and provide label or description of substance
Most Critical Symptoms: Severe burning, pain, blistering, vision loss, coughing, abdominal pain

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, alcohol-resistant foam, dry chemical powder, or carbon dioxide for small fires
Unsuitable Media: High-volume water jet can splash and spread corrosive liquid
Specific Hazards: Burning releases sulfur oxides, pungent toxic fumes, and sometimes irritating aerosols
Firefighter Protection: Wear self-contained breathing apparatus, flame-resistant gear, acid-resistant gloves, and boots; stay upwind
Special Precautions: Isolate area, prevent leaks from entering waterways, cool exposed containers with spray

Accidental Release Measures

Personal Protection: Don chemical apron, splash goggles, acid-resistant gloves, and respiratory mask
Environmental Precautions: Stop material from leaking into soil, sewers, or natural water sources; use dikes or booms for larger spills
Cleanup Methods: Absorb small spills with inert material like sand, sweep and shovel into chemical-waste drums for disposal; neutralize residue with diluted sodium carbonate or limestone slurry; ventilate area thoroughly; decontaminate tools and surfaces

Handling and Storage

Safe Handling: Do not eat, drink, or smoke while handling; pour slowly in well-ventilated place; avoid all unnecessary contact; survey containers before opening for possible pressure buildup from fumes
Storage Conditions: Store tightly sealed in corrosive-resistant containers, out of sunlight and moisture, below 30°C; isolate away from oxidizing agents, strong alkalis, and metals prone to corrosion
Incompatibles: Alkalis, oxidizers, organic peroxides, strong reducers, reactive metals such as sodium, potassium, magnesium
Transfer Procedures: Use a grounded system to avoid static discharge, rely on approved chemical pumps or glassware, label secondary containers

Exposure Controls and Personal Protection

Exposure Limits: No ACGIH established limit, but workplace air concentrations kept below 1 mg/m³ as a precaution
Engineering Controls: Local exhaust ventilation, chemical fume hood for laboratory work, emergency eyewash and shower stations in work area
Personal Protection: Full-face shield, chemical splash goggles; impervious gloves (neoprene, nitrile, or butyl rubber); acid-resistant apron, sleeves, boots; NIOSH-approved respirator if dust or mist forms
Hygiene Measures: Wash skin thoroughly after any contact; keep contaminated clothing away from home laundry; use barrier creams if available

Physical and Chemical Properties

Appearance: White to off-white crystalline powder or granules; sometimes has a faint aromatic odor
pH: Strongly acidic in dilute water solution
Melting Point: 150–153°C
Boiling Point: Decomposes before boiling
Solubility: Readily dissolves in water, ethanol; low solubility in hydrocarbons
Density: About 1.37 g/cm³
Vapor Pressure: Negligible at ambient temperature
Flash Point: Data not applicable (non-flammable solid under normal conditions)
Odor Threshold: Not available due to weak odor profile

Stability and Reactivity

Chemical Stability: Remains stable in dry, sealed containers under normal storage; absorbs moisture from air and deliquesces
Conditions to Avoid: Direct sunlight, excessive heat, high humidity, and open air exposure
Incompatible Materials: Attacks most metals, reacts with bases and strong oxidizers quickly; avoid mixing with chlorine-releasing agents
Hazardous Decomposition: Sulfur oxides (SOx), carbon oxides, volatile organic byproducts from breakdown
Polymerization: Does not self-polymerize

Toxicological Information

Exposure Effects: Rapid skin or eye contact triggers severe irritation or burns, long-lasting damage possible if not washed off quickly; ingestion leads to mouth, throat, esophagus injuries; breathing dust irritates nose, lungs, may cause cough, chemical pneumonitis
Acute Toxicity: LD50 (oral, rat) estimated near 300–500 mg/kg; rapid onset symptoms after exposure by any route
Chronic Effects: No strong evidence of long-term toxicity at low doses; repeated exposure or chronic irritation can sensitize skin or mucous membranes, trigger asthma in susceptible workers
Carcinogenicity: No classification as carcinogen by IARC, ACGIH, NTP, or OSHA

Ecological Information

Aquatic Toxicity: Harmful to aquatic organisms, especially at high concentrations; encourages algae blooms, shifts pH of natural water
Persistence and Degradability: Breaks down slowly in soil and water, risk of bioaccumulation minimal; natural reduction mainly through microbial action
Soil Mobility: Soluble, migrates rapidly in ground and surface water, possibility of contaminating wells if released
Other Harmful Effects: Large spills damage vegetation, disrupt aquatic habitats, kill fish and aquatic invertebrates

Disposal Considerations

Disposal Methods: Consult licensed hazardous waste contractor; neutralize liquid waste using weak base, confirm neutral pH, deposit in approved hazardous landfill
Container Cleaning: Triple-rinse containers, treat rinse water as hazardous; never reuse emptied containers for food or drink
Disposal Restrictions: Never pour down the drain or mix with domestic waste; apply local, state, and federal disposal regulations strictly

Transport Information

UN Number: UN2581
Proper Shipping Name: Xylene sulfonic acids, solid
Hazard Class: 8 (Corrosive)
Packing Group: II
Labels Required: Corrosive (8), marine pollutant as needed for bulk
Special Precautions: Keep packaging upright, intact; train drivers in spill handling, rapid communication

Regulatory Information

GHS Classification: Corrosive to skin (Category 1B), Serious eye damage (Category 1)
OSHA: Hazardous under OSHA Hazard Communication Standard
TSCA: Listed substance in Toxic Substances Control Act inventory
SARA Title III: Not subject to specific reporting under Sections 302/304/313; general hazard communication applies
State Right-to-Know: Subject to reporting and labeling for emergency preparedness
Other Regulations: Subject to local workplace exposure limits; proper hazard labeling required for all storage, transport, and export