Product Name: (1R)-7,7-Dimethyl-2-Oxobicyclo(2.2.1)Hept-1-ylmethanesulphonic Acid
Synonyms: Camphor-10-sulfonic acid, KSA, CSA
Recommended Use: Research reagent, chemical intermediate
Supplier: Manufacturer or distributor details available on request
Emergency Contact: Refer to local poison center or supplier emergency line
CAS Number: 5872-08-2
UN Number: UN3261 (when transported as a corrosive solid)
Classification: Corrosive to metals, skin, and eyes
GHS Label Elements: Danger symbol showing corrosion
Hazard Statements: Causes severe skin burns and eye damage; corrosive to metals; may cause respiratory irritation
Precautionary Statements: Avoid contact with skin and eyes; use only in well-ventilated areas; avoid release to the environment
Hazard Pictograms: Corrosion, exclamation mark
Signal Word: Danger
Routes of Exposure: Inhalation, skin contact, eye contact, ingestion
Potential Health Effects: Burning, blindness, pulmonary irritation, tissue damage, GI disturbance
Chemical Name: (1R)-7,7-Dimethyl-2-Oxobicyclo(2.2.1)Hept-1-ylmethanesulphonic Acid
Concentration: 95–100% by weight
Impurities: Trace solvents or unreacted camphor derivatives (less than 1%)
Molecular Formula: C10H16O4S
Molecular Weight: 232.3 g/mol
General Instructions: Remove contaminated clothing and wash affected areas thoroughly
Inhalation: Move person to fresh air, support breathing if needed, seek medical attention immediately
Skin Contact: Rinse skin with running water for a minimum of 15 minutes, do not delay removal of contaminated clothing, get medical help
Eye Contact: Rinse eyes cautiously with water for at least 15 minutes, keep eyelids open, seek immediate medical attention
Ingestion: Rinse mouth thoroughly, do not induce vomiting, give small amounts of water if conscious, obtain medical attention as a priority
Suitable Extinguishing Media: Carbon dioxide, dry chemical powder, alcohol-resistant foam
Unsuitable Extinguishing Media: Water jets produce splatter, can spread corrosive material
Hazardous Combustion Products: Sulfur oxides, carbon monoxide, carbon dioxide
Special Protective Gear for Firefighters: Full protective clothing, self-contained breathing apparatus
Fire/Explosion Hazards: Vapors corrosive; thermal decomposition emits toxic fumes
Fire-Fighting Procedures: Avoid runoff from fire control into sewers; cool exposed containers with water spray
Personal Precautions: Wear acid-resistant clothing, gloves, splash goggles
Environmental Precautions: Prevent material from entering soil, ditches, waterways
Cleanup Methods: Neutralize with sodium bicarbonate or lime, absorb with inert material, collect in suitable waste containers for disposal
Ventilation: Use local exhaust or move spill outdoors
Decontamination: Wash contaminated surfaces with dilute sodium carbonate
Handling: Work under chemical fume hood or ventilated area, avoid dust formation, wear protective clothing, do not eat, drink, or smoke during use
Storage Conditions: Store in tightly closed containers corrosion-resistant, out of reach of incompatible substances (strong bases, metals, oxidizers), maintain in cool, dry location
Special Sensitivities: Hygroscopic, avoid exposure to moisture and extreme temperatures
Incompatibilities: Bases, amines, alcohols, active metals, water-reactive substances
Engineering Controls: Chemical-resistant benches, fume extraction, splash barriers
Eye Protection: Safety goggles or face shield
Hand Protection: Butyl rubber or nitrile gloves preferred
Skin Protection: Acid-resistant lab coat, apron
Respiratory Protection: NIOSH-approved respirator if dust or vapor above threshold
Hygiene Measures: Wash hands before breaks and after work, remove contaminated clothing immediately
Appearance: White to off-white crystalline powder
Odor: Faint camphoraceous
Boiling Point: Decomposes before boiling
Melting Point: 180–190°C (356–374°F)
Solubility: Appreciable in water and most polar organic solvents
pH: Acidic in solution
Vapor Pressure: Negligible at room temperature
Density: 1.35–1.40 g/cm³
Viscosity: Not applicable
Flash Point: Not determined
Evaporation Rate: Not available
Partition Coefficient: Log Kow not determined
Chemical Stability: Stable under recommended storage conditions away from light and moisture
Decomposition: Heat and humidity accelerate breakdown, releases sulfur oxides
Reactivity: Reacts violently with strong bases, active metals, oxidizers
Hazardous Reactions: Exothermic with caustics; reacts with metals to evolve hydrogen
Polymerization: Does not polymerize
Conditions to Avoid: Excess heat, contact with alkali, exposure to moisture
Acute Toxicity: Data limited, corrosivity suggests significant risk if swallowed or inhaled
Irritation: Severe skin, eye, and respiratory irritant
Sensitization: Not fully evaluated, reactions possible with chronic or repeat exposure
Chronic Exposure: Repeated contact may produce dermatitis, respiratory system irritation, ulceration
Carcinogenicity/Mutagenicity: No evidence from current literature
LD50 (Oral, rat): Not precisely determined, corrosive nature presumed dangerous
Signs of Overexposure: Redness, blistering, burns, cough, shortness of breath, abdominal pain
Aquatic Toxicity: Substance hazardous to aquatic life at high concentrations
Degradability: Component likely to biodegrade slowly in water
Bioaccumulation: No strong evidence for bioaccumulation in aquatic organisms
Mobility: Water-soluble, potential to migrate in soil and water
Environmental Impact: Spills can acidify local waters, disrupt soil biology, kill aquatic invertebrates if concentrations high
Precautions: Avoid release or disposal into drains, surface waters, and groundwater
Waste Treatment Methods: Treat chemically to neutralize acidity, collect in properly labeled hazardous waste containers
Disposal: Use licensed hazardous waste management service
Contaminated Packaging: Dispose as hazardous waste after thorough rinsing and neutralization
Disposal Regulations: Observe local, regional, and national regulations for chemical waste
UN Number: UN3261
Proper Shipping Name: Corrosive solid, acidic, organic, n.o.s. ((1R)-7,7-Dimethyl-2-Oxobicyclo(2.2.1)Hept-1-ylmethanesulphonic Acid)
Transport Hazard Class: 8 (corrosive substances)
Packing Group: II or III, depending on concentration and form
Special Transport Requirements: Keep away from incompatible materials, moisture, direct sunlight
Emergency Response Guide: Use ERG guide for corrosive organic acids
OSHA Status: Hazardous chemical by OSHA definition
TSCA Inventory: Listed or reporting required
SARA Title III: Not listed under Sections 302, 304, or 313
REACH: Substance subject to annual volume restrictions, restrictions on use in consumer products
Labeling Requirements: Corrosive pictogram, GHS signal word Danger
Other Regulations: Complies with global transport and workplace safety rules for corrosive organic acids, may require reporting under local fire and environmental codes
